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Updated: Jul 1, 2025

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
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Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization

Published on: November 27, 2015

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过渡金属甲基基氧 (PHENI*) 复合物的结构和乙烯聚合反应的趋势

Clement G Collins Rice1, Justin A Hayden1, Adam D Hawkins1

  • 1Chemistry Research Laboratory, Department of Chemistry, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, U.K.

Organometallics
|March 1, 2024
PubMed
概括

新的甲基基氧 (PHENI*) 催化剂在乙烯聚合方面表现出异常活力,产生超高分子量聚乙烯 (UHMWPE),具有更好的金属可访问性和催化效率.

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Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)

Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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