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Updated: Jul 1, 2025

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基于阿佐基诺林的分子光开关的多重控制

Youming Lv1,2, Hebo Ye1, Lei You1,2,3

  • 1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou 350002 China lyou@fjirsm.ac.cn.

Chemical science
|March 1, 2024
PubMed
概括

研究人员使用阿佐基诺林支架开发了复杂的分子开关. 这些多响应系统通过光,pH,金属离子和胺来精确控制E/Z光异构.

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Aryldiazonium Salts to Azo Dyes: Diazo Coupling01:11

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the...
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