在动力力下,基于的非对称单化异半常规聚合物的增强N型半导体性能
Younghyo Kim1, Kyoungtae Hwang2, Dongseong Yang1
1School of Materials Science and Engineering (SMSE), Gwangju Institute of Science and Technology (GIST), Gwangju 61005, Republic of Korea.
ACS applied materials & interfaces
|March 1, 2024
概括
不对称的单化产生了新的基于isoindigo的聚合物. 在有机场效应晶体管中,P1CIID-2T聚合物显示出增强的分子排序和改善的电子流动性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 有机电子 有机电子
背景情况:
- 传统的二化策略面临着严峻的挑战.
- 开发新的受体单元对于先进的聚合物设计至关重要.
- 半常规聚合物具有可调节的电子特性.
研究的目的:
- 合成非对称的单化异 (1CIID) 作为一种新型的受体单元.
- 将1CIID与不同的捐赠单位 (2T和DTBT) 共聚合,以形成新的聚合物.
- 研究由此产生的聚合物的结构-性质关系,特别是有机场效应晶体管 (OFETs).
主要方法:
- 在isoindigo上选择性地引入单个原子.
- 单化异 (1CIID) 与2,2'-二二烯 (2T) 和4,7-二二二) [1,2,5]亚 (DTBT) 的联合聚合.
- 聚合物性质的表征,包括骨干线性,双极时刻,通过X射线衍射的薄膜形态和OFET性能.
主要成果:
- 成功合成单化异 (1CIID).
- 形成两个聚合物,P1CIID-2T和P1CIID-DTBT,具有不同的结构和电子特性.
- 具有中心对称的2T单元的P1CIID-2T表现出线性脊柱,高二极矩 (10.20 D) 和高度有序的结晶性.
- P1CIID-2T在动力力下表现出显著的分子对齐,导致OFET的性能提高了8倍,电子移动性高达1.22厘米V-1s-1.
结论:
- 非对称单化是一种可行的策略,用于创建先进的受体单元和半区域常规聚合物.
- 捐赠单位的对称性显著影响了聚合物骨干线性和双极时刻.
- 作为高性能有机电子产品的n型半导体,P1CIID-2T显示出巨大的潜力.
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