沉:微型-石墨烯复合材料的快速合成,用于长寿命的离子电池
Yuto Katsuyama1, Yang Li1, Sophia Uemura1
1Department of Chemistry & Biochemistry, University of California Los Angeles, Los Angeles, California 90095-1569, United States.
ACS applied materials & interfaces
|March 1, 2024
概括
一种新的修改后的沉方法可以为离子电池制造碳包裹的微粒 (SiMP). 这种可扩展的技术使SiMP/石墨烯复合材料的周期寿命翻了一番,提高了电池的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术 纳米技术
背景情况:
- 微粒 (SiMP) 为离子电池阳极提供高容量,但由于体积膨胀,其周期寿命较低.
- 现有的改善SiMP循环性能的方法,如碳包装,是复杂的,不能扩展.
研究的目的:
- 开发一种简单,快速,可扩展的方法来制造碳包装的SiMP.
- 为了提高基于SiMP的离子电池阳极的循环稳定性和性能.
主要方法:
- 一种修改后的沉方法,涉及将石墨烯氧化物 (GO) 和SiMP分散剂注入n-hexane.
- 激光切割SiMP/GO薄膜,将GO减少到激光切割石墨烯 (LSG),并在SiMP上形成保护性SiO2和SiC层.
主要成果:
- 修改后的沉方法成功地在SiMPs周围创建了GO的包装结构.
- 激光切割同时减少了GO并形成了保护层,减轻了SiMP体积变化.
- 通过这种方法生产的SiMP / 石墨烯复合材料的周期寿命与物理混合复合材料相比翻了一番 (50.2%与24.0%的保留在第100个周期).
结论:
- 修改后沉法是一种可扩展和有效的策略,用于合成SiMP/碳复合材料.
- 这种方法显著提高了SiMP阳极的循环性能,为下一代离子电池提供了一个有前途的替代方案.
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