作为储能应用的潜在电极材料,MWCNT辅助碳化物MXene的增强电化学性能
M Waqas Hakim1, Irfan Ali1, Sabeen Fatima1
1Physics Characterization and Simulations Lab (PCSL), Department of Physics, School of Natural Sciences (SNS), National University of Sciences and Technology (NUST), Islamabad 54000, Pakistan.
ACS omega
|March 4, 2024
概括
一种新的Mo2TiC2Tx MXene复合物与碳纳米管显著提高了超级电容器的性能. 这种MXene材料的特定电容增加了四倍,非常适合用于储能应用.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- 像MXenes这样的二维 (2D) 材料提供了显著的结构灵活性.
- 通过选择性蚀刻,从MAX阶段合成MXenes.
研究的目的:
- 准备Mo2TiC2TxMXene和一个复合物与多壁碳纳米管 (MWCNTs).
- 为了提高超级电容器应用的电化学性能.
主要方法:
- 对Mo2TiAlC2Tx MAX相进行选择性化学蚀刻,以产生Mo2TiC2Tx MXene.
- 复合形成的Mo2TiC2Tx MXene与CTAB移植的MWCNTs.
- 使用结构,形态,元素,振动和表面分析技术进行表征.
- 在1M KOH电解质中使用循环电量计和静电电荷放电来评估电化学性能.
主要成果:
- 这种Mo2TiC2Tx MXene的特定电容为425 Fg-1.1.
- 这种MWCNTs@Mo2TiC2Tx复合材料在5mVs-1.1下显著增强了1740 Fg-1 (几乎增加了四倍) 的特定电容.
- 与原始的MXene相比,复合物显示出更好的电化学性能和反应动力学.
结论:
- 这种MWCNTs@Mo2TiC2Tx复合材料具有卓越的电化学性能.
- 性能提升归因于增加的活性表面积和提高的导电性.
- 这种复合材料是先进超级电容应用的有希望的候选者.
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