离散快速的富里埃变换辅助紫外线-红外线双共振光谱仪用于气溶探测和识别
Marjan Rajaei Ramsheh1, Mohammad Mahdi Doroodmand1
1Department of Chemistry, College of Science, Shiraz University, Shiraz, Iran. Doroodmand@shirazu.ac.ir.
The Analyst
|March 4, 2024
概括
一种新型的光谱法准确地检测和识别各种气溶,使用数字多功能磁盘作为低成本格子. 这一进步为环境监测提供了更好的灵敏度和检测极限.
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 频谱学是一种光谱学.
背景情况:
- 气溶检测对于环境监测和空气质量评估至关重要.
- 现有的气溶分析方法可能昂贵而复杂.
- 需要准确,精确和易于使用的气溶检测技术.
研究的目的:
- 引入一种新,低成本,准确的气溶检测和识别分析方法.
- 证明开发的系统对各种气溶的定量和定性分析的能力.
- 改进气溶分析的灵敏度和检测极限.
主要方法:
- 开发一种基于阵列的光谱方法,使用离散快速里埃变换 (dFFT) 辅助的双共振紫外线-红外线光谱.
- 实现数字多功能磁盘 (DVD) 切片作为一个具有成本效益的,大小可控制的波长选择器 (格子) 和光反射器.
- 软件控制的操作,用于精确分析和实时检测.
主要成果:
- 开发的方法实现了各种气溶的准确和精确检测和识别,包括烟雾,烟雾,基微/纳米粒子和碳烟.
- 该系统证明适用于实时检测化学剂修饰颗粒的适用性.
- 获得了可接受的灵敏度和选择性,并提高了检测极限.
结论:
- 新型光谱法为气溶分析提供了可靠且具有成本效益的解决方案.
- 使用DVD片作为格子为光谱学提供了一种简单且易于使用的方法.
- 这种技术有望加强环境监测和空气质量管理.
相关概念视频
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation
219
Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
There are three main types of inductively coupled plasma atomic emission spectroscopy (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
219
Ultraviolet and Visible (UV–Vis) Spectroscopy: Overview
2.6K
Ultraviolet–visible (UV–visible or UV–Vis) spectroscopy is an analytical technique that investigates the interaction between matter and UV–Vis light within the electromagnetic spectrum. This method is widely used for its versatility, simplicity, and relatively quick data acquisition, making it valuable for both qualitative and quantitative analysis. When UV–Vis radiation passes through a material, molecules absorb light depending on the energy required for...
2.6K
UV–Vis Spectrometers
1.3K
The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell.
1.3K
IR Spectrometers
1.1K
There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
1.1K
IR Frequency Region: Fingerprint Region
887
IR spectra are divided into two main regions: the diagnostic region and the fingerprint region. The diagnostic region of the spectrum lies above 1500 cm−1. The absorptions resulting from single-bond vibrations of the N–H, C–H, and O–H stretch at higher wavenumbers and appear on the left side of the spectrum. The stretching absorptions of the C≡C and C≡N occur between 2100–2300 cm−1. In contrast, those arising from stretching absorptions of the...
887
Atomic Emission Spectroscopy: Instrumentation
391
The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers. Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.
391


