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Updated: Jul 1, 2025

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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解反应性差异:室温环开转化聚合 (ROMP) 与前端ROMP

Jacob J Lessard1, Edgar B Mejia2, Abbie J Kim1

  • 1Beckman Institute for Advanced Science and Technology, Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, Illinois 61801, United States of America.

Journal of the American Chemical Society
|March 5, 2024
PubMed
概括

前环开放转化聚合 (FROMP) 提供了对树脂反应性的增强控制,改善了寿命和聚合速度. 在FROMP系统中,较高的启动度意外地提高了性能.

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...
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