从使用低毒性基二醇制成的环氧树脂制成的热的初步研究
Olena Shafranska1, Catherine Sutton2, Deep Kalita1
1Department of Coatings and Polymeric Materials, North Dakota State University, Fargo, ND, 58108, USA.
Macromolecular rapid communications
|March 6, 2024
概括
基于的环氧树脂为基于双A (BPA) 的系统提供了更安全的替代方案. 这些新型热在热稳定性和材料性能方面表现相似,使它们成为可行的BPA替代品.
科学领域:
- 聚合物科学 聚合物科学
- 材料化学 材料化学
- 可持续化学 可持续化学
背景情况:
- 双-A (BPA) 是一种广泛使用的环氧树脂前体,已知有毒性问题.
- 出于环境和健康原因,开发更安全的替代BPA基环氧树脂至关重要.
- 基于的化合物为生物基和低毒性材料开发提供了潜力.
研究的目的:
- 合成和表征基于的二醇及其衍生的二甲乙烯.
- 评估这些新型环氧树脂的热稳定性和耐热性质.
- 评估以为基础的热作为BPA基环氧树脂的潜在替代品的性能.
主要方法:
- 合成基于的二醇及其转化为二甲基乙烯.
- 在高温下用异二胺 (IPDA) 固化二甲基乙烯.
- 热性质的表征,包括玻璃过渡温度 (Tg),硬度,粘合力和弹性.
主要成果:
- 基于的迪格利基乙烯已成功制备并固化成热固体.
- 与原始二极管相比,热固体表现出更好的热稳定性.
- 玻璃过渡温度在30-54°C之间,受二醇结构的影响.
- 钢材上的涂层表现出高硬度,良好的粘合力和灵活性,与基于BPA的对照相美.
结论:
- 来自 furan 二醇的环氧树脂的毒性概况低于基于 BPA 的系统.
- 这些基于的热聚合剂的性能特性与传统的BPA环氧树脂相美.
- 基于的环氧树脂是传统BPA环氧树脂的可行和可持续的替代品.
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