Ho3+-doped BaGd2 ZnO5绿色发射用于固态照明:合成,表征和光发光特性
Irfan Ayoub1, Vijay Kumar1,2
1Department of Physics, National Institute of Technology Srinagar, Srinagar, Jammu and Kashmir, India.
概括
我们使用固态反应合成绿色发射的BaGd2ZnO5:Ho3+. 这些光体具有出色的光学性能,适用于显示器和照明应用.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 发光的光度是非常的低的.
背景情况:
- 开发高效的光剂对于先进的照明和显示技术至关重要.
- 稀土合氧化物材料为各种应用提供可调节的光学性能.
研究的目的:
- 为了合成和描述一种新的绿色发射,BaGd2ZnO5:Ho3+.
- 为了研究 (Ho3+) 兴奋剂度对材料结构和光学性能的影响.
主要方法:
- 合成的高温固态反应方法.
- 用X射线粉碎衍射 (XRD) 分析相纯度和晶体结构.
- 扩散反射光谱,扫描电子显微镜 (SEM) 和飞行时间二次离子质谱 (ToF-SIMS) 用于光学和形态特征.
主要成果:
- 阶段纯的BaGd2ZnO5:Ho3+被成功合成.
- 光体呈现出4.65 eV的宽带间隙.
- 观察到以540nm为中心的强烈绿色辐射,归因于Ho3+ (5F4 + 2S2 → 5I8过渡).
- 在绿色区域的CIE坐标 (0.285,0.705) 实现了高颜色纯度 (99.6%).
结论:
- 合成的BaGd2ZnO5:Ho3+体显示出出色的绿色发光特性.
- 该材料显示出在绿色发射器件,包括显示器和白色发光二极管 (WLED) 中应用的巨大潜力.
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