两性介质层调节的界面聚合,用于构建聚胺纳米过膜,具有高性选择性单/双盐
Xin Zhang1, Xu Zhang1, Lushen Xu1
1Center for Membrane and Water Science & Technology, Collaborative Innovation Center of Membrane Separation and Water Treatment of Zhejiang Province, Zhejiang University of Technology, Hangzhou 310014, China.
ACS applied materials & interfaces
|March 6, 2024
概括
研究人员开发了先进的薄膜复合材料 (TFC) 膜,使用一种新型的两性介质层. 这项创新显著提高了离子分离性能,解决了工业应用的选择性-透性权衡问题.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 膜技术 膜技术 膜技术
背景情况:
- 薄膜复合材料 (TFC) 膜对于分离单价离子和双价离子至关重要.
- 选择性-透性权衡仍然是TFC膜开发中的一个重大挑战.
- 精确控制选择性层的结构是困难的.
研究的目的:
- 为了合成高质量的TFC膜,提高选择性和透性.
- 为了克服选择性-透性的权衡,使用一个功能性的两性中间层.
- 为构建基于聚胺的膜提供一种多功能方法.
主要方法:
- 使用的聚多巴胺 (PDA) 具有长链的功能,作为两性中间层.
- 采用封闭的界面聚合反应 (IP) 来形成聚胺 (PA) 活性层.
- 研究了中间层对聚合和孔隙结构的影响.
主要成果:
- 两性中间层促进了均的PA聚合和均的孔径分布.
- 通过D-8/PA膜获得了高NaCl/Na2SO4分离因子204.07.
- 膜流量增加到25.71 L m-2 h-1 bar-1.0 的时间.
结论:
- 功能性两性中间层对于制造高性能TFC膜是有效的.
- 这种方法为开发多功能,高选择性聚胺膜提供了一个可行的策略.
- 开发的膜对需要精确离子分离的工业应用非常有希望.
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