使用离子液体提取碳化合物
Gangqiang Yu1, Chengna Dai1, Ning Liu1
1Faculty of Environment and Life, Beijing University of Technology, 100 Ping Le Yuan, Chaoyang District, Beijing 100124, China.
Chemical reviews
|March 6, 2024
概括
离子液体 (ILs) 为碳化合物分离提供了可持续的替代品,提高了效率,并减少了诸如芳提取和脱硫等过程中的能源消耗. 本综述详细介绍了IL的应用,机制以及化学分离的未来潜力.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
背景情况:
- 化学工业中的分离过程耗费大量能源,碳化合物净化是石油炼油的主要挑战.
- 提取中使用的传统有机溶剂存在溶剂损失,污染,低效率和高再生能等问题.
- 离子液体 (IL) 已成为先进化学分离工艺的有希望的可设计溶剂.
研究的目的:
- 为使用离子液体 (ILs) 进行提取式碳化合物分离提供最先进进展情况的全面审查.
- 涵盖包括分子建模,结构属性关系,分离机制和工业规模工艺设计在内的关键方面.
- 将讨论扩展到IL类似物和深度性溶剂 (DES),概述当前的挑战和未来的机遇.
主要方法:
- 对IL系统的分子热力学模型进行审查,以预测相位平衡和选IL候选者.
- 分析ILs的离子组件及其分离性能 (选择性,分布系数) 之间的结构性质关系.
- 检查与IL相关的提取分离机制,重点关注分子间相互作用.
- 基于验证的热力学模型进行过程模拟和工业规模设计的讨论.
主要成果:
- ILs显示出显著的潜力,以提高碳化合物分离的效率和可持续性,如芳提取,脱硫和脱.
- 分子热力学模型有助于快速选和准确预测在分离过程中的IL行为.
- 了解IL结构-性质关系和分子间相互作用对于优化分离性能至关重要.
- 经过验证的模型可以模拟和设计工业规模的基于IL的提取过程.
结论:
- 离子液体比传统的提取性碳化合物分离溶剂具有显著的进步,提供更高的效率和更少的环境影响.
- 系统性审查涵盖了分子到工艺尺度,为IL应用和未来研究方向提供了宝贵的参考.
- 进一步开发IL类似物和深度性溶剂 (DES) 对应当前的挑战和扩大化学分离中的应用具有前景.
相关概念视频
Extraction: Advanced Methods
446
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
446
Ion-Exchange Chromatography
486
Ion-exchange chromatography, or IEC, is a technique for separating ions based on their affinity for the stationary phase. The stationary phase is a cross-linked polymer resin with covalently attached ionic functional groups. The functional groups can be either positively charged (cation exchangers) or negatively charged (anion exchangers). A cation exchanger consists of a polymeric anion and active cations, while an anion exchanger is a polymeric cation with active anions. The choice of...
486
Entropy and Solvation
7.1K
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
7.1K
Ion Exchange
592
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
592
High-Performance Liquid Chromatography: Elution Process
477
In High-Performance Liquid Chromatography (HPLC), the elution process is critical to the separation of analytes and the quality of chromatographic results. Elution describes how compounds move through the column and separate based on their interactions with the mobile and stationary phases. This process determines the resolution, peak shape, and retention times in the chromatogram, which are essential for identifying and quantifying components in complex mixtures. Understanding the elution...
477
Supercritical Fluid Chromatography
247
Supercritical fluid chromatography (SFC) provides a beneficial substitute for gas chromatography (GC) and liquid chromatography (LC) for certain samples because it merges the top attributes of both techniques. SFC allows the separation and analysis of compounds that GC or LC does not easily manage. These compounds are traditionally nonvolatile or thermally unstable, making GC unsuitable and lacking functional groups required for HPLC analysis.
SFC utilizes a supercritical fluid mobile phase,...
SFC utilizes a supercritical fluid mobile phase,...
247


