将织污泥再循环转化为氧化水泥:物理特性,微观结构和浸出行为
Zhi-Hai He1, Ya-Qian Ni2, Jin-Yan Shi3
1College of Civil Engineering, Shaoxing University, Shaoxing 312000, China; Key Laboratory of Rock Mechanics and Geohazards of Zhejiang Province, Shaoxing 312000, China.
The Science of the total environment
|March 6, 2024
概括
织污泥灰 (TSA) 增强了氧化水泥 (MOC) 的重金属固化作用. 添加TSA可以改善MOC.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 化学工程是化学工程的重要组成部分.
背景情况:
- 织物污泥是一种废水副产品,含有危险的重金属,对环境构成风险.
- 氧化水泥 (MOC) 正因其对这些有害物质固化的潜力而受到探索.
研究的目的:
- 研究织污泥灰 (TSA) 对MOC的机械性能和微观结构的影响.
- 评估TSA修改的MOC在结织污泥中的重金属中的有效性.
主要方法:
- 将TSA的不同百分比纳入MOC配方.
- 评估MOC样品的压力强度,耐水性和体积稳定性.
- 使用纳米技术和孔隙结构评估进行微结构分析.
- 液分析以确定重金属固化效率.
主要成果:
- 添加5%-20%的TSA提高了空气固化MOC糊的压力强度和耐水性.
- 通过加入TSA,通过形成Mg-Al-Cl-Si-H和Mg-Cl-Si-H凝,增强了体积膨胀和改善了水的稳定性.
- MOC有效地固化了重金属;Ni无法检测,Zn和Mn的固化在20%的TSA样本中超过99%.
结论:
- TSA是MOC的有益添加剂,增强其机械性能和水稳定性.
- 经过TSA修改的MOC证明了在织污泥中有效固化重金属的绝佳潜力.
- 这种方法为管理织行业废水副产品提供了一个可持续的解决方案.
更多相关视频
相关概念视频
Hydration of Cement
232
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
232
Types of Cement II
108
Portland blast-furnace cement is made by blending Portland cement clinker with granulated blast-furnace slag, which accounts for 25 to 65 percent of the cement's weight. Despite its similarities to ordinary Portland (Type I) cement in terms of fineness and setting times, its early strength is lower, though it achieves comparable strength later on. It's particularly suited for mass concrete structures and marine environments due to its lower heat of hydration and superior sulfate...
108
Corrosion of Reinforcement
182
The corrosion of steel reinforcement within concrete is a process influenced by the material's inherent properties and external factors. The high pH level of around 13, provided by calcium hydroxide present in concrete, initially protects the steel reinforcement by promoting the formation of a passive iron oxide layer on its surface.
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
182
Effect of Sea Water on Concrete
229
Concrete exposed to seawater can undergo degradation like the dissolution of ettringite and gypsum, increasing the material's porosity and decreasing its strength. In contrast, the crystallization of salts within the concrete's pores can cause expansion, particularly above the waterline where evaporation occurs. Nonetheless, this expansion only happens when seawater, enabled by the concrete's permeability, manages to infiltrate the structure.
Concrete in areas between tide marks,...
Concrete in areas between tide marks,...
229
Fineness of Cement
131
The fineness of cement directly influences the rate of hydration, as the hydration begins at the surface of the cement particles. In addition to hydration, the fineness of cement is vital for various properties of concrete including workability, gypsum requirement, and long-term behavior. The fineness of cement is represented in terms of the specific surface of cement which is typically measured in square meters per kilogram, with several methods available for this determination.
Direct...
Direct...
131


