无形Se的结构,粘合和电子特性
Chong Qiao1, Lanli Chen1, Rongchuan Gu2
1School of Mathematics and Physics, Nanyang Institute of Technology, Nanyang 473004, China.
Physical chemistry chemical physics : PCCP
|March 7, 2024
概括
无形 (Se) 形成稳定,长链,对Ovonic值切换 (OTS) 选择器至关重要. 这项研究揭示了Se Se.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 计算化学的计算化学
背景情况:
- 电极值切换 (OTS) 选择器提高了相位变换内存密度,减少了泄漏.
- 无形日耳曼化物 (GeSe) 是一个关键的OTS材料,但它的功能成分,无形 (Se),是研究不足的.
- 了解无形Se对于优化基于Se的OTS选择器应用程序至关重要.
研究的目的:
- 研究无形 (Se) 的结构,结合和电子特性.
- 阐明无形Se与其在OTS设备中的作用相关的基本特征.
主要方法:
- 使用了*ab initio*的分子动力学模拟.
- 分析了原子结构,结合配置和电子状态.
主要成果:
- 确定了Se原子形成2个协调配置的倾向,从而形成长而稳定的链条.
- 计算出高的Se-Se键形成能量 (4.44 eV),表明了重要的键稳定性.
- 在无形的Se中观察到的中隙状态,与OTS行为相关,尽管它们的比例较低.
结论:
- 无形Se具有稳定的链结构,具有强大的Se-Se键.
- 中间隙状态的存在证实了无形Se在OTS应用中的潜力.
- 这项研究加深了对无形Se的理解,支持开发基于Se的先进OTS选择器.
更多相关视频
09:23Author Spotlight: Advancing Energy Solutions Using Nanocomposites as Processed Thermoelectric Materials
Published on: May 17, 2024
1.6K
08:12Ohmic Contact Fabrication Using a Focused-ion Beam Technique and Electrical Characterization for Layer Semiconductor Nanostructures
Published on: December 5, 2015
12.3K
相关概念视频
Energy Bands in Solids
858
Isolated atoms have discrete energy levels that are well described by the Bohr model. And, it quantifies the energy of an electron in a hydrogen atom as En. Higher quantum numbers 'n' yield less negative, closer electron energy levels.
Band Formation:
When atoms are brought close together, as in a solid, these discrete energy levels begin to split due to the overlap of electron orbitals from adjacent atoms. This split occurs because of the Pauli exclusion principle, which states...
Band Formation:
When atoms are brought close together, as in a solid, these discrete energy levels begin to split due to the overlap of electron orbitals from adjacent atoms. This split occurs because of the Pauli exclusion principle, which states...
858
Structures of Solids
14.1K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
14.1K
VSEPR Theory and the Basic Shapes
68.3K
Overview of VSEPR Theory
68.3K
Trends in Lattice Energy: Ion Size and Charge
23.9K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
23.9K
Types of Semiconductors
597
Intrinsic semiconductors are highly pure materials with no impurities. At absolute zero, these semiconductors behave as perfect insulators because all the valence electrons are bound, and the conduction band is empty, disallowing electrical conduction. The Fermi level is a concept used to describe the probability of occupancy of energy levels by electrons at thermal equilibrium. In intrinsic semiconductors, the Fermi level is positioned at the midpoint of the energy gap at absolute zero. When...
597
Scanning Electron Microscopy
4.2K
A scanning electron microscope (SEM) is used to study the surface features of a sample by using an electron beam that scans the sample surface in a two-dimensional manner. Typically, areas between ~1 centimeter to 5 micrometers in width can be imaged. SEM can be used to image bacteria, viruses, tissues as well as larger samples like insects. Conventional SEM gives a magnification ranging from 20X to 30,000X and spatial resolution of 50 to 100 nanometers.
Fundamental Principles
Accelerated...
Fundamental Principles
Accelerated...
4.2K
