揭示了氧独特的可逆双电子转移过程和稳定氧介质,用于高性能水性离子电池
Jiaoyi Ning1, Xiaopeng Zhang2, Dongjiu Xie3
1State Key Laboratory of Coal Mine Disaster Dynamics and Control, School of Chemistry and Chemical Engineering, Multi-Scale Porous Materials Center, Institute of Advanced Interdisciplinary Studies, Chongqing University, No. 174 Shazheng Street, Shapingba District, Chongqing, 400044, China.
Angewandte Chemie (International ed. in English)
|March 7, 2024
概括
氧表现出可逆的两电子氧化还原特性,显著提高水性离子电池 (ZIB) 的容量. 在有机电极材料中的这一突破为先进的ZIB应用提供了高性能和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水性离子电池 (ZIB) 中的P型阴极材料由于受到限制的电子转移而受到低特异容量的限制.
- 增强多电子传输对于提高ZIB中的电荷存储能力至关重要.
研究的目的:
- 为了研究可逆的多电子氧化还原性质的phenoxazine在水性电解质的高性能ZIBs.
- 阐明基于氧的电极的氧化还原化学机制和结构稳定性.
主要方法:
- 在水性电解质中对诺的电化学表征.
- 使用先进的分析技术研究氧化还原中间体和结构稳定性.
- 在水性ZIB中对氧电极的性能评估.
主要成果:
- 氧在水性电解质中表现出可逆的两电子氧化还原特性,其中介物是稳定的基 (PNO•+) 和二 (PNO2+).
- 增强的芳香度在氧化还原循环过程中提供了卓越的结构稳定性.
- 氧电极在3500个周期内实现215 mAh g-1的高容量和100%的容量保留.
结论:
- 氧是由于其多电子转移能力而成为高性能水性ZIB的p型有机电极材料.
- 稳定的氧化还原中间体和结构完整性有助于卓越的电化学性能.
- 这项研究推动了下一代储能设备的有机电极的开发.
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