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Updated: Jul 1, 2025

Monitoring the Reductive and Oxidative Half-Reactions of a Flavin-Dependent Monooxygenase using Stopped-Flow Spectrophotometry
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Published on: March 18, 2012

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非血红素Fe的异常催化策略 (二) /2-氧格酸盐依赖的阿斯巴提尔氧酶AspH

Anandhu Krishnan1, Sodiq O Waheed1, Ann Varghese1

  • 1Department of Chemistry, Michigan Technological University Houghton MI 49931 USA tatyanak@mtu.edu.

Chemical science
|March 8, 2024
PubMed
概括

AspH酶使用独特的铁结合水分子进行立体选择性C-H化,与其他2 - 氧格酸盐 (2OG) 化酶不同. 这种机制涉及原子转移和反弹步骤,为生物催化剂工程提供了洞察力.

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