[4-(2-氨基乙烯) 吗啡-κ2,N']二基:合成,晶体结构和希尔什菲尔德表面分析
B Chidambaranathan1, S Sivaraj1, P Vijayamathubalan1
1PG and Research Department of Physics, Government Arts College for Men (Autonomous), Nandanam, Chennai 600 035, Tamil Nadu, India.
概括
一种新的基于的协调化合物被合成使用4-(2-aminoethyl) morpholine和(II) 化物. 晶体结构显示出由键和金属-连接体相互作用形成的3D网络.
科学领域:
- 协调化学 协调化学
- 晶体工程公司 晶体工程公司
- 材料科学 材料科学 材料科学
背景情况:
- 金属有机框架和协调聚合物由于其多样化的应用而引起人们的兴趣.
- 了解金属复合物的超分子组合对于设计新材料至关重要.
研究的目的:
- 为了合成和表征一种新的 ((II) 协调化合物与4- (((2-氨基乙基) 摩尔.
- 为了研究合成化合物中的晶体结构和超分子相互作用.
主要方法:
- 单晶X射线衍射的X射线衍射方法
- 合成 ((II) 复合物的合成.
- 希尔什菲尔德表面分析
主要成果:
- 标题化合物[CdBr2(C6H14N2O) ]进行了合成和表征.
- 晶体结构由一个中心对称的二元体组成,其中有一个六坐标的原子,在扭曲的八面体几何学中.
- 聚合物双链和3D网络通过各种分子间相互作用形成,包括OCd,C-HO,C-HBr和N-HBr气键.
- 希尔什菲尔德表面分析表明,HH和BrH/HBr相互作用是结晶包装的主要贡献者.
结论:
- 该研究成功合成了一种具有独特3D网络结构的新型协调化合物.
- 晶体包装主要由结合和金属结合物相互作用来控制,其中N-HBr结合物发挥着重要作用.
- 这些发现有助于理解基于的协调复合体中的晶体工程原理.
相关概念视频
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02:42Valence Bond Theory
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02:52Stereoisomerism
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