在饮用水消毒中胺衰变的局部增强混合顺序模型
Weinan Feng1, Wencheng Ma1, Dan Zhong1
1State Key Laboratory of Urban Water Resource and Environment, School of environment, Harbin Institute of Technology, Harbin 150090, PR China.
本研究引入了一种简化的局部增强混合顺序 (LEM) 模型,以准确预测饮用水中的胺衰变. 新模型通过更好地模拟随时间推移的消毒剂度来提高水质安全.
科学领域:
- 环境化学环境化学
- 水处理技术水处理技术
- 化学动力学 化学动力学
背景情况:
- 胺是饮用水中的关键消毒剂,但其度必须在配电系统内仔细管理.
- 了解胺分解机制对于优化消毒和确保水安全至关重要.
研究的目的:
- 开发和验证一种新的,准确的模型来模拟胺在水中的衰变.
- 通过证明参数温度依赖而不是初始度依赖来简化现有模型.
主要方法:
- 提出了局部增强的混合顺序 (LEM) 模型,结合了第一顺序和混合顺序的衰变组件.
- 通过将关键参数 (a 和 k2) 与温度相关联,简化了 LEM 模型.
- 在不同初始度和温度下进行了9次胺衰变实验,以测试模型.
主要成果:
- 简化的LEM模型有效地模拟了整个胺衰变过程.
- 与传统的第一顺序和混合顺序模型相比,LEM模型显示出更高的精度 (更高的R2,更低的SSE).
- 基于温度依赖的参数简化得到了验证.
结论:
- 简化的LEM模型为模拟胺衰变提供了强大而准确的方法.
- 这种模式对优化饮用水消毒和确保公共卫生安全具有重大影响.
- 这些发现支持在水分网中更好地管理消毒剂残留物.
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