研究氧化热效应的相互合特性和含气煤的微观结构演变
Rongkun Pan1, Tan Zhang2, Hailin Jia1
1School of Safety & Science Engineering, Henan Polytechnic University, Jiaozuo 454003, China; Collaborative Innovation Center of Coal Work Safety and Clean High Efficiency Utilization, Henan Polytechnic University, Jiaozuo 454003, China; Henan Key Laboratory of Prevention and Cure of Mine Methane & Fires, Jiaozuo 454003, China.
这项研究研究了不同气体压力下的煤炭氧化. 增加的气体压力增强了煤炭的多孔性,通过促进热气交换,可能增加自发燃烧风险.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 煤层在采矿过程中受到限制和周围压力的影响.
- 了解含有气体的煤炭中的氧化和自燃对于安全至关重要.
研究的目的:
- 为了研究不同气体压力下的煤炭氧化过程中的热释放和微观结构演变.
- 探索气相转换和气相迁移对氧化和自燃的影响.
主要方法:
- 不同扫描热量计 (DSC)
- 里埃变换红外光谱法 (FTIR) 是一种
- 入孔径测试 (MIP) 是一种入孔径测试.
主要成果:
- 在更高的温度下,甲的迁移会抑制氧气吸附,延迟热量的积累.
- 高气压与煤炭松性和多孔性增加有关.
- 高温会增强高压含气煤中的孔隙连接,增加自燃风险.
结论:
- 气体压力显著影响煤炭氧化和自燃.
- 在更高的温度下增强的孔隙连接性增加了含气煤的自燃风险.
- 这些发现对于预防和预测含有气体的煤矿中自燃的发生至关重要.
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