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Updated: Jul 1, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Published on: November 21, 2017

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对N-乙烯基碳醇的立体选择性阴离子聚合的机械洞察

Cole C Sorensen1, Vittal Bhat1, Anthony Y Bello1

  • 1Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599, United States.

ACS catalysis
|March 12, 2024
PubMed
概括

非对称离子配对 (AIP) 催化使得立体规律的聚合物合成成为可能. 这项研究揭示了控制策略性的竞争步骤和影响阴离子乙烯聚合物的螺旋性的复杂因素,指导未来的催化剂设计.

关键词:
N-乙烯基碳醇是一种不对称的离子配对阴离子聚合的聚合物.螺旋-感觉-选择性的选择性战术性 战术性 战术性

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