加速器对使用流体催化裂解催化剂残留物 (FCC) 的水泥砂的影响:在早期固化年龄时增强机械性能
Lourdes Soriano1, María Victoria Borrachero1, Ester Giménez-Carbo1
1Giquima-Research Group of Building Materials Chemistry, Instituto Universitario de Investigación de Ciencia y Tecnología del Hormigón ICITECH, Universitat Politècnica de València, 46022 Valencia, Spain.
Materials (Basel, Switzerland)
|March 13, 2024
概括
加速添加剂显著提高了流体催化裂变催化剂残留物 (FCC) 砂的早期机械强度. 商用添加剂SKR表现出卓越的性能,在短短8小时内将压力强度提高了100%以上.
科学领域:
- 建筑材料科学 建筑材料科学
- 化学工程是化学工程的重要组成部分.
- 废弃物价值化 废弃物价值化 废弃物价值化
背景情况:
- 补充性水泥材料 (SCM) 减少了波特兰水泥对环境的影响.
- 流体催化裂变催化剂残留物 (FCC),一种石化废物,是一种高度反应性的SCM.
- 基于SCM的粘合剂通常在早期阶段表现出较低的机械强度.
研究的目的:
- 评估加速度添加剂 (KOH,酸,SKR) 对FCC砂机械强度的影响.
- 确定FCC结合剂中早期力量发展的最佳加速器.
- 评估FCC与加速器的长期性能和兼容性.
主要方法:
- 使用FCC作为SCM制备砂.
- 添加不同的加速剂:KOH,酸盐 (SIL) 和商业添加剂 (SKR).
- 在各种固化年龄 (8小时,24小时,48小时,28天) 进行压力强度测试.
- 热重力测量分析 (TGA) 来确认兼容性.
主要成果:
- 与普通FCC砂 (12.8MPa) 相比,使用SKR的FCC砂在8小时后 (26.0MPa) 显示了超过100%的压力强度增长.
- 在早期力量发展 (8-24小时) 中,SKR显著超过KOH和SIL.
- 加速器的有效性顺序随着时间的推移而变化:KOH ≈ SIL < SKR (8-24h) 和KOH < SIL < SKR (48h-28天).
- TGA证实了FCC和商业加速器SKR之间的良好兼容性.
结论:
- 加速添加剂,特别是SKR,有效提高FCC型迫击炮的早期机械强度.
- 通过适当的加速器,FCC可以有效地被用作补充的水泥材料.
- 该研究为使用工业废物开发可持续建筑材料提供了宝贵的见解.
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