从激活的红泥粒子吸附剂中酸盐脱落的机制
Zhiwen Yang1,2,3, Longjiang Li1,2,3, Yalan Wang1,2,3
1Mining College, Guizhou University, Guiyang 550025, China.
Molecules (Basel, Switzerland)
|March 13, 2024
概括
活性红泥有效地消耗,达到99.11%的去除率. 这项研究揭示了单分子层化学溶解是主要的,受温度和化学反应的影响.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 红色泥是生产的副产品,它带来了处理方面的挑战.
- 从废物中回收对于资源的可持续性至关重要.
- 活化红泥显示出作为吸附剂的潜力,用于去除.
研究的目的:
- 为了研究从激活的红泥中的脱落机制.
- 为了确定最佳条件,以实现高效的溶解.
- 为了阐明释放所涉及的化学和物理过程.
主要方法:
- 使用盐酸 (HCl) 溶液进行溶解试验.
- 检查最佳的吸附性参数:度,剂量,温度和时间.
- 使用兰迈尔等温法,伪二次动力学和粒子内部扩散模型进行分析.
- 热力学分析和富里埃变换红外光谱法 (FTIR).
主要成果:
- 在特定的HCl度,剂量,温度和时间下,达到99.11%的酸盐去除 (11.29 mg/g) 的最佳脱吸.
- 单分子层表面脱附是主要的,具有化学脱附动力学.
- 高温可以促进的自发脱落.
- 溶解涉及Ca,Al和Fe的溶解以及功能组的变化,FTIR证实了这一点.
结论:
- 活性红泥是一种有效的材料,用于脱.
- 溶解过程主要由单分子层化学相互作用来控制.
- 优化条件和理解机制有助于的回收和红泥的价值化.
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