关于从水溶液中去除Cr (VI) 的动力学和热力学研究,使用酸修饰的香皮 (ABP) 吸附剂
Zhouyang Huang1, Robyn Campbell1, Chirangano Mangwandi1
1School of Chemistry and Chemical Engineering, Queen's University Belfast, David Kier Building, Stranmillis Road, Belfast BT95AG, Northern Ireland, UK.
Molecules (Basel, Switzerland)
|March 13, 2024
概括
经过酸改性香皮提供了一种具有成本效益的解决方案,用于从废水中去除有毒的 (VI). 这种环保吸附剂表现出高效率和容量,使其成为净化水的有希望的材料.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 香皮废弃物是一种易于获得的,低成本的资源.
- 六价 (Cr (VI)) 是工业废水中的有毒污染物.
- 开发高效和可持续的吸附剂对于环境修复至关重要.
研究的目的:
- 调查酸修饰香皮作为Cr (VI) 去除吸附剂的有效性.
- 描述吸附的特性和机制.
- 评估Cr (VI) 回收的可能性.
主要方法:
- 香皮粉是用硫酸 (H2SO4) 处理的.
- 进行吸附实验以确定最佳条件 (剂量,度,温度).
- 采用了吸附同热量,动力学,热力学和FTIR分析.
主要成果:
- 酸性修饰显著增加了表面积和Cr (VI) 吸附能力 (161 mg/g).
- 吸附遵循伪二次动力学和兰格穆尔等热法.
- 这一过程是自发的,内热的,并表明物理吸收与Cr (VI) 减少到Cr (III).
- 酸性条件允许36%的Cr回收,而中性pH导致不可逆转的吸附.
结论:
- 经过酸改性香皮是一种高效,低成本和环保的吸附剂,用于去除Cr (VI).
- 吸附剂促进了Cr (VI) 的降解和结合功能组.
- 存在废水处理和资源回收的潜力.
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