硫酸腐蚀对石浮动性能的影响,通过改变表面粗度
Dingquan Xing1, Ruofan Sun1, Shuai Ma1
1Inner Mongolia Research Institute of CUMTB, Key Laboratory of Separation and Processing of Symbiotic-Associated Mineral Resources in Non-Ferrous Metal Industry, Engineering Technology Research Center for Comprehensive Utilization of Rare Earth-Rare Metal-Rare Scattered in Non-Ferrous Metal Industry, School of Chemical & Environmental Engineering, China University of Mining & Technology (Beijing), Beijing 100083, China.
硫酸腐蚀显著降低石表面粗性和疏水性,导致矿物浮动性能差. 这项研究详细介绍了对石浮性和表面性能的有害影响.
科学领域:
- 矿物加工 矿物加工
- 表面化学 表面化学
- 材料科学 材料科学 材料科学
背景情况:
- 表面粗度极大地影响矿物浮动效率.
- 了解矿物表面的变化是优化分离过程的关键.
研究的目的:
- 为了研究硫酸腐蚀对石表面粗度的影响.
- 分析对石漂浮性能的后续影响.
主要方法:
- 进行了微浮试验,以评估漂浮性.
- 使用扫描电子显微镜与能量分散光谱 (SEM-EDS) 和原子力显微镜 (AFM) 分析了表面形态和粗度.
- 表面化学的特点是里埃变换红外光谱 (FT-IR) 和接触角度测量.
主要成果:
- 硫酸处理严重降低了石的浮性,在4mL (3mol/L) 的剂量下恢复率降至19%以下.
- SEM-EDS和AFM揭示了表面形态的显著变化,平均表面粗度的降低和表面积的减少.
- 对FT-IR和接触角度的分析表明,表面的水友性增强,酸吸附率降低.
结论:
- 硫酸腐蚀通过降低表面粗性和疏水性而对石浮动产生负面影响.
- 表面形态和化学的改变,包括减少活性Ca2+位点,解释了漂浮性能的下降.
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