通过冲击诱导相变的黑的格拉姆尺度合成
Jinchao Qiao1, Haotian Ran2, Qiang Zhou3
1State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, 100081 Beijing, China.
Inorganic chemistry
|March 14, 2024
概括
冲击波将红色转化为黑色,使用一种新的装置. 在最佳条件下,可以获得高品质的黑粉,从而实现具有成本效益的工业生产.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 纳米技术 纳米技术
背景情况:
- 黑 (BP) 是一个有前途的二维材料,具有独特的电子和光学特性.
- 目前的BP合成方法通常涉及高温,有毒试剂或低产量.
- 开发可扩展和具有成本效益的BP生产方法对于其广泛应用至关重要.
研究的目的:
- 通过使用冲击波负载,研究无形红色 (rP) 完全相变为黑色 (BP).
- 为了确定这种转换的最佳冲击压力和温度.
- 开发一种简单,具有成本效益和高收益的方法来生产高质量的BP.
主要方法:
- 使用一个圆柱形的双管冲击装载装置.
- 无形红色被用作前体材料.
- 通过不同的冲击压力和温度参数进行了实验.
- 回收的样本以相位组成和微观结构进行了表征.
主要成果:
- 在特定的冲击条件下,将无形的rP完全转换为形BP.
- 确定了最佳条件:9 GPa的压力和800 K的温度.
- 成功制备了具有优异结晶度的高质量的orthorhombic BP粉末.
- 冲击装载方法被证明是简单的,具有成本效益和高收益率.
结论:
- 冲击波诱导的相变是一种合成黑的有效方法.
- 优化的冲击负荷参数使得生产高质量的BP粉末成为可能.
- 这种方法为工业规模生产黑提供了有前途的途径,降低了成本,并允许更广泛的应用.
相关概念视频
Phase Transitions: Melting and Freezing
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
Schwarzschild Radius and Event Horizon
No object with a finite mass can travel faster than the speed of light in a vacuum. This fact has an interesting consequence in the domain of extremely high gravitational fields.
The minimum speed required to launch a projectile from the surface of an object to which it is gravitationally bound so that it eventually escapes the object’s gravitational field is called the escape velocity. The escape velocity is independent of the mass of the object. Merging the idea of escape velocity with the...
The minimum speed required to launch a projectile from the surface of an object to which it is gravitationally bound so that it eventually escapes the object’s gravitational field is called the escape velocity. The escape velocity is independent of the mass of the object. Merging the idea of escape velocity with the...
Detection of Black Holes
Although black holes were theoretically postulated in the 1920s, they remained outside the domain of observational astronomy until the 1970s.
Their closest cousins are neutron stars, which are composed almost entirely of neutrons packed against each other, making them extremely dense. A neutron star has the same mass as the Sun but its diameter is only a few kilometers. Therefore, the escape velocity from their surface is close to the speed of light.
Not until the 1960s, when the first neutron...
Their closest cousins are neutron stars, which are composed almost entirely of neutrons packed against each other, making them extremely dense. A neutron star has the same mass as the Sun but its diameter is only a few kilometers. Therefore, the escape velocity from their surface is close to the speed of light.
Not until the 1960s, when the first neutron...
Forced Transdifferentiation
Transdifferentiation, also known as lineage reprogramming, was first discovered by Selman and Kafatos in 1974 in silkmoths. They observed that the moths’ cuticle-producing cells transformed into salt-producing cells. Many such cases of natural transdifferentiation occur in organisms. In humans, pancreatic alpha cells can become beta cells. In newts, the loss of the eye’s lens causes the pigmented epithelial cells to transdifferentiate into the lens cells.
Artificial transdifferentiation occurs...
Artificial transdifferentiation occurs...
Gauss's Law
If a closed surface does not have any charge inside where an electric field line can terminate, then the electric field line entering the surface at one point must necessarily exit at some other point of the surface. Therefore, if a closed surface does not have any charges inside the enclosed volume, then the electric flux through the surface is zero. What happens to the electric flux if there are some charges inside the enclosed volume? Gauss's law gives a quantitative answer to this question.
Gauss's Law: Planar Symmetry
A planar symmetry of charge density is obtained when charges are uniformly spread over a large flat surface. In planar symmetry, all points in a plane parallel to the plane of charge are identical with respect to the charges. Suppose the plane of the charge distribution is the xy-plane, and the electric field at a space point P with coordinates (x, y, z) is to be determined. Since the charge density is the same at all (x, y) - coordinates in the z = 0 plane, by symmetry, the electric field at P...


