含的碳管由光照射制造出来的
Kanade Matsui1, Kenshin Yamamoto1, Keigo Oyama1
1Division of Applied Chemistry, Environmental and Biomedical Engineering Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan.
Langmuir : the ACS journal of surfaces and colloids
|March 14, 2024
概括
研究人员用用聚烯 (PPy) 涂覆的棉纤维制成含碳 (NCC) 管. 尼尔射线激光或阳光将PPy外转化为NCC,形成有控制直径和厚度的空心管.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 聚合物化学 聚合物化学
背景情况:
- 聚烯 (PPy) 是一种具有光热特性的导电聚合物.
- 含碳 (NCC) 材料由于其独特的特性而具有多种应用.
- 开发高效的合成NCC材料的方法至关重要.
研究的目的:
- 用一种新光热转换方法合成含碳 (NCC) 管.
- 探索使用棉/聚烯 (PPy) 纤维作为NCC管制造的前体.
- 为了研究光源和PPy外厚度对NCC管特性的影响.
主要方法:
- 棉花芯/聚烯 (PPy) 盖纤维是通过水性化学氧化种子聚合合成的.
- 接近红外线 (NIR) 激光照射或太阳光被用于光热转换,分解棉芯并将PPy转换为NCC.
- 扫描电子显微镜 (SEM),元素微分析,里埃变换红外光谱 (FTIR) 和拉曼光谱被用于表征.
主要成果:
- 观察到具有单分散直径的空心管的形成.
- 该PPy被成功转化为含碳 (NCC).
- 管的厚度可以通过调整PPy外厚度,从410nm调整到2.30μm.
- 该方法证明可以应用于其他聚合物纤维,如烯酸和羊毛.
结论:
- 从聚合物/PPy纤维制造NCC管的一种简单且可扩展的方法.
- 使用NIR激光或太阳光的光热转换为NCC合成提供了有效的途径.
- 由此产生的NCC管的形态密切模仿了前体聚合物/PPy纤维.
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