胆固醇液晶聚合物网络的循环极化发光与欧洲 (III) 复合物作为发射器
Liting Xu1, Fengyun Shi1, Jinghua Zhao1
1State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, PR China.
ACS applied materials & interfaces
|March 14, 2024
概括
在胆固醇液晶聚合物网络 (CLCN) 中嵌入了一种新的欧 (III) 协调复合物,以创建可调节的循环极化发光 (CPL) 材料. 这些CPL活跃的CLCN片显示出防伪和加密应用的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 有机化学 有机化学
- 光子学 是一个光子学.
背景情况:
- 协调复合体具有独特的光物理特性.
- 胆固醇液晶聚合物网络 (CLCNs) 能够实现可调节的光学特征.
- 循环极化发光 (CPL) 对于先进的光学应用至关重要.
研究的目的:
- 合成一个具有高量子产量的欧 (III) 协调复合体.
- 将复合物嵌入用于CPL活性材料的CLCN中.
- 探索反假冒和加密中的应用.
主要方法:
- 综合的Eu(C12C12dbm) 3(phen) 协调复合体. 这是一个复杂的组合.
- 将复合物嵌入CLCN膜和PMMA层中.
- 关于CPL特性和片性能的描述.
主要成果:
- 获得了高量子收益率 (∼51.9%) 的Eu(III) 复合体.
- 在CLCN电影中,证明了可调节的CPL手性,具有高的glum 值 (高达0.63).
- 创建了具有增强的光值 (∼1.42) 和独特的光模式的复合系统.
结论:
- 协调化合物可以有效地与CLCN集成,以产生CPL活性材料.
- 由于可调节的CPL和独特的成像,开发的材料具有防伪和加密的潜力.
- 这项研究为基于CLCN的功能材料开辟了新途径.
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