兼容性与反应扩散:决定聚合粘合剂网络异质性的因素
Denghao Fu1, Sarah Beth Holles1, Emily England1
1Department of Chemical Engineering & Materials Science, Michigan State University, East Lansing MI 48824, USA.
牙粘合剂配方具有较低的疏水性和疏水性比率,并添加辅溶剂,显示异质性和相位分离的增加. 了解聚合动力学和扩散对于预测材料相位结构至关重要.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 生物材料是一种生物材料.
背景情况:
- 牙粘合剂中的网络聚合通常会导致异质性和相位分离,损害材料性能.
- 控制牙粘合剂的微架构对于提高其耐用性和临床成功至关重要.
研究的目的:
- 调查疏水性交叉连接剂对疏水性共聚物比率 (C/H比率) 和辅溶剂分量的对模型牙粘合剂配方异质性和相位分离的影响.
- 阐明配方成分,聚合动力学和牙粘合剂的相位形态之间的关系.
主要方法:
- 研究了12种不同C/H比率 (7:1到0.5:1) 和辅溶剂分数 (0.10,20%重量%) 的配方.
- 使用里叶变换红外光谱 (FT-IR),动态机械分析 (DMA),小角度X射线散射 (SAXS) 和原子力显微镜 (AFM) 描述异质性和相位行为.
主要成果:
- 没有辅溶剂的树脂显示异质性减少,C/H比较低.
- 加入10-20%重量的辅溶剂诱导了显著的异质性和相位分离,特别是在较低的C/H比率下.
- 分相域范围从数百纳米到几微米.
结论:
- 较低的C/H比率和添加的辅溶剂通过延迟聚合过程中的扩散限制来促进相分离.
- 在特定的动力条件下,热力学驱动的相位分离是最受欢迎的.
- 预测牙粘合剂相位结构需要考虑聚合动力学和扩散约束,而不仅仅是成分兼容性.
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