使用硫化石墨烯氧化物从水溶液中去除水晶紫色的实验和计算研究
Olayinka Oluwaseun Oluwasina1, Adedeji Adebukola Adelodun2,3, Olugbenga Oludayo Oluwasina4
1Department of Marine Science and Technology, The Federal University of Technology, P.M.B. 704, Akure, 340110, Nigeria. oluwasinaoo@futa.edu.ng.
Scientific reports
|March 15, 2024
概括
硫化石墨烯氧化物 (GO-SO3H) 有效地从水中去除阴阳晶紫色染料. 这种吸附剂显示出快速,自发和内热吸附,使其成为废水处理的有希望的材料.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 纳米技术纳米技术
背景情况:
- 石墨烯氧化物 (GO) 的功能化增强了其吸附性质.
- 像水晶紫色 (CV) 这样的阴阳性染料是常见的水污染物.
- 硫酸功能化引入硫酸组,增加正电荷的吸引力.
研究的目的:
- 为了合成和表征硫化石墨烯氧化物 (GO-SO3H) 用于阴阳性染料吸附.
- 为了研究GO-SO3H的吸附机制和功能的CV去除.
- 评估pH值,度和温度对吸附效率的影响.
主要方法:
- 对GO-SO3H的合成和表征.
- 批量吸附实验研究CV去除.
- 动力学,异热学和热力学分析.
- 计算方法以阐明吸附机制.
主要成果:
- GO-SO3H显示出高CV吸附能力,在不同温度下达到97.65-202.5毫克·g−1.
- 在30分钟内迅速达到吸附平衡.
- 伪二阶动力模型和兰格穆尔等热法最好地描述了吸附过程.
- 热力学研究表明自发和内热吸附.
结论:
- GO-SO3H 是一种高效的吸附剂,用于从水溶液中去除阴阳性染料.
- 吸附过程是高效的,快速的,并由有利的热力学条件驱动.
- 这种功能化石墨烯氧化物显示出污水处理应用的巨大潜力.
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