响应酸的聚乙烯-Na+组件具有独特的红蓝色转变颜色
Rungarune Saymung1, Ruttayapon Potai2, Christine M Papadakis3
1Laboratory of Advanced Polymers and Nanomaterials, School of Materials Science and Innovation, Faculty of Science, Mahidol University at Salaya, Phuttamonthon 4 Road, Salaya, Nakhon Pathom, 73170, Thailand.
Heliyon
|March 15, 2024
概括
本研究介绍了一种简单的方法,使用氧化来制造酸敏聚乙烯 (PDA). 这些新的PDA在暴露在酸中时呈现出从红色到蓝色的颜色变化,增强了色度测量传感应用.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
背景情况:
- 聚乙烯 (PDA) 是一种对刺激有反应的聚合物,对色度检测有价值.
- 标准的PDAs具有碳酸基头组缺乏酸诱导的色度反应.
- 修改PDA头组以适应酸敏感性通常需要复杂的合成.
研究的目的:
- 开发一种简单且具有成本效益的方法,用于创建对酸有反应的PDA.
- 为了研究10,12-tricosadiynoic酸 (TCDA) 和氧化 (NaOH) 的联合组装,以开发适应酸的材料.
- 为了探索合成的PDAs对酸的色度反应.
主要方法:
- 同时组装TCDA和多余NaOH,然后进行低温化和光聚合.
- 由此产生的多 (TCDA-Na+) 组件的特征.
- 组件在水和气相中暴露于化 (HCl),以观察色度变化.
主要成果:
- 红相聚合物 (TCDA-Na+) 组件通过与NaOH联合组装成功合成.
- 在暴露于HCl时,观察到明显的红色到蓝色的颜色转变.
- NaOH和TCDA的度影响了PDA的分子组织,形态和酸敏感性.
结论:
- 已经证明了一种简单且廉价的方法来生产对酸有反应的PDA.
- 开发的PDA显示了扩展色度传感应用的潜力,特别是用于酸检测.
- 这种方法绕过了PDA头组复杂的功能化需求.
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