通过n型SnTe的逐步优化实现全基于SnTe的热电发电
Tao Hong1, Bingchao Qin1, Yongxin Qin1
1School of Materials Science and Engineering, Beihang University, Beijing 100191, China.
Journal of the American Chemical Society
|March 15, 2024
概括
研究人员优化了n型锡化物 (SnTe) 热电,以高效的中温发电. 他们实现了0.75的峰值值 (ZT),使得第一个全SnTe热电装置具有2.7%的转换效率.
科学领域:
- 材料科学
- 固态物理
- 能源转换
背景情况:
- 高性能n型和p型热电材料对于实际设备应用至关重要.
- 环境友好的锡化物 (SnTe) 是有前途的,但开发高性能的n型SnTe是必不可少的.
- 现有的p型SnTe研究需要可比的n型对应物来提高设备的可靠性.
研究的目的:
- 为了优化n型SnTe的热电传输特性.
- 为中温发电开发一种高性能的n型SnTe材料.
- 制造和评估一个完全基于SnTe的热电装置.
主要方法:
- 步骤优化策略涉及PbSe合金,以缩小带间隙并增强n类型的可用性.
- 引入额外的Pb原子来补偿阴离子空位并增加电子载体度.
- 使用优化的n型SnTe制造完全基于SnTe的七对热电装置.
主要成果:
- 在573 K的温度下,n型SnTe的最高热电功率 (ZT) 达到了0.75.
- 在广泛的温度范围内获得高平均ZT (ZTave) 超过0.5 (300823K).
- 在350K的温度差异下,全SnTe装置的最大输出功率为~0.2W和2.7%的转换效率.
结论:
- 逐步优化策略显著提高了n型SnTe的热电性能.
- 开发的n型SnTe对中温发电应用具有很好的潜力.
- 这种全SnTe装置的成功制造标志着一个突破,突出了基于SnTe的热电的可行性.
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