热稳定的Pd/CeO2@SiO2具有用于催化瘦甲燃烧的核心外结构
Linyan Tan1, Ganghua Xiang1, Zhigang Liu1
1Advanced Catalytic Engineering Research Centre of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China. liuzhigang@hnu.edu.cn.
Nanoscale
|March 18, 2024
概括
贵金属催化剂对于瘦甲 (CH4) 燃烧是有效的,但会使其失效. 一种新的核心外催化剂 (Pd/CeO2@SiO2) 在CH4燃烧中显著提高了热稳定性和性能.
科学领域:
- 催化剂是一种催化剂.
- 材料科学 材料科学 材料科学
- 环境化学环境化学
背景情况:
- 贵金属催化剂对瘦甲 (CH4) 燃烧具有很高的活性.
- 纳米粒子催化剂由于高表面能量而面临通过迁移和聚合的失活.
研究的目的:
- 设计和合成一个热稳定的核心外催化剂,以增强精益CH4燃烧.
- 为了提高贵金属催化剂的禁用电阻.
主要方法:
- 在SiO2外中封装的Pd/CeO2核心的合成 (Pd/CeO2@SiO2).
- 使用各种技术进行表征,以确认结构和稳定性.
- 对于稀薄CH4燃烧的催化活性测试.
主要成果:
- 成功合成了具有增强热稳定的Pd/CeO2@SiO2.
- 在385°C时,Pd/CeO2@SiO2实现了90%的CH4转化,在多次运行后在440°C时超过了Pd/CeO2.
- 核心外结构限制了Pd纳米粒子的迁移和聚合.
结论:
- Pd/CeO2@SiO2核心外催化剂表现出优越的热稳定性和用于精益CH4燃烧的催化性能.
- 增强的金属支相互作用和SiO2外的保护有助于提高催化剂的耐用性和活性.
- 催化剂促进了Pd-Ce-O固体溶液和活性氧物种的形成,提高了氧化还原能力.
相关概念视频
Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes
6.3K
The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
6.3K
Turnover Number and Catalytic Efficiency
10.1K
The turnover number of an enzyme is the maximum number of substrate molecules it can transform per unit time. Turnover numbers for most enzymes range from 1 to 1000 molecules per second. Catalase has the known highest turnover number, capable of converting up to 2.8×106 molecules of hydrogen peroxide into water and oxygen per second. Lysozyme has the lowest known turnover number of half a molecule per second.
Chymotrypsin is a pancreatic enzyme that breaks down proteins during digestion....
Chymotrypsin is a pancreatic enzyme that breaks down proteins during digestion....
10.1K
Catalysis
26.9K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
26.9K
Thermal and Photochemical Electrocyclic Reactions: Overview
2.3K
Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
2.3K
Thermal Electrocyclic Reactions: Stereochemistry
2.0K
The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
2.0K
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
10.1K
Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
10.1K


