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Updated: Jun 30, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Published on: November 21, 2017

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一个C-C西格玛键的异构化路径在一个 bis{\octaazamacrocycle}dinickel{\}II) 复合体中被deprotonation激活:一个DFT研究

Ingrid Jelemenska1, Michal Zalibera1, Peter Rapta1

  • 1Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Radlinského 9, 81237 Bratislava, Slovak Republic.

Theoretical chemistry accounts
|March 18, 2024
PubMed
概括

研究了一种脱的 (II) 八马克罗环二聚体的反同同化. 脱质化促进了几何扭曲,揭示了异构化途径中的关键中间体.

关键词:
反-syn 同位体是反-syn 同位体.在 DFT 方面,它是最重要的.异构化途径 异构化途径复合体是复合物的一个组成部分.潜在能量表面的表面.扫描扫描扫描 扫描扫描

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The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
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