在不同的固化条件下研究一个环氧树脂导热粘合剂的热力学特性和形态学
Cheng Zhang1, Zhe Xu1, Yingxuan Huang1
1School of Science, Shanghai Institute of Technology, Shanghai 201418, China.
ACS omega
|March 18, 2024
概括
优化环氧树脂导热粘合剂的固化条件显著提高了性能. 特殊条件如150°C/2.5小时和超分支固化剂可以提高热稳定性,性和剪切强度高达307%.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 热力工程是热力工程中的一个.
背景情况:
- 环氧树脂导热粘合剂是多功能耐热聚合物.
- 它们的热力学特性对固化条件非常敏感.
- 类填充剂用于增强导热性.
研究的目的:
- 研究各种固化条件对环氧树脂导热粘合剂的影响.
- 探索固化剂在增强粘附性和性方面的作用.
- 为了优化这些粘合剂的性能,以改善热和机械性能.
主要方法:
- 使用球形烯酸填充剂和多阶段冷混合方法制备环氧树脂导热粘合剂.
- 固化条件 (温度和时间) 的系统变化.
- 评估热力学性能,剪切强度,玻璃过渡温度,热分解和断裂形态.
主要成果:
- 150°C/2.5小时的固化条件显著提高了粘合性能.
- 超分支固化剂增强了性和粘附性,增加了高达307%的剪切强度.
- 增加的固化温度和时间导致更高的玻璃过渡温度 (103.9159.8 °C) 和更好的热稳定性 (初始分解温度295.4310.1 °C).
- 骨折形态从脆性转变为柔性,经过优化治愈.
结论:
- 固化条件极大地影响了环氧树脂粘合剂的导热性和热稳定性.
- 优化的固化参数和新型固化剂可以显著提高粘合性能.
- 研究结果为改善环氧树脂粘合剂应用和生产效率提供了宝贵的见解.
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