离子分布对聚电解质复合体凝中应力松的影响
Alexey A Gavrilov1,2, Elena Yu Kramarenko1,3
1Faculty of Physics, Lomonosov Moscow State University, 119991 Moscow, Russia.
The Journal of chemical physics
|March 19, 2024
概括
多电解质溶液形成具有交叉连接的物理凝. 它们的机械性能取决于电荷的排列,导致弹性或粘弹性反应,具有不同的放松时间.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
背景情况:
- 含有相等比例的聚和聚离子的多电解液可以形成物理凝.
- 这些凝的特点是由充电组之间的静电相互作用形成的物理交叉链接.
研究的目的:
- 研究聚电解质物理凝的机械性能和结构.
- 了解在聚合物骨干和Bjerrum长度沿线的电荷排列如何影响凝的行为.
- 探索分子结构和宏观机械反应之间的关系.
主要方法:
- 研究聚电解质凝系统对单轴亲系变形的反应.
- 分析应力放松曲线以确定机械性能和放松时间.
- 研究粘弹性系统中网络结构的时间演变.
主要成果:
- 多电解质系统根据其机械反应被分为三组:弹性,长放松粘可弹性和短放松粘可弹性.
- 带有间隔器上的电荷系统显示没有稳定的聚合物,这表明电荷流动性增加.
- 压力放松曲线表现出多样化的功能形式,表明至少有两个特征性的放松时间.
- 在具有较长放松时间的系统中观察到动态聚合物,有助于子链形态放松.
结论:
- 沿着多电解质骨干的电荷布局是决定物理凝的机械反应和放松行为的关键因素.
- 聚合物的存在和动态显著影响这些系统的粘弹性特性.
- 了解电荷分布,Bjerrum长度和网络动态之间的相互作用是设计具有量身定制性质的多电解质凝的关键.
相关概念视频
Problem Solving on Stress and Strain
738
Stress is a quantity that describes the magnitude of a force that causes deformation, generally defined as internal force per unit area. When forces pull on an object and cause its elongation, like the stretching of an elastic band, it is called tensile stress. When forces cause the compression of an object, it is known as compressive stress. When an object is being squeezed uniformly from all sides, like a submarine in the depths of the ocean, we call this kind of stress bulk stress (or volume...
738
SDS-PAGE
27.9K
Gel electrophoresis is a method that separates biological macromolecules like nucleic acids or proteins by forcing them to pass through a gel matrix under an electric field.
A variation of gel electrophoresis, termed polyacrylamide gel electrophoresis (PAGE), is commonly used for separating proteins according to their molecular size by passing them through a polyacrylamide gel. Because of the varying charges associated with amino acid side chains, PAGE can be used to separate intact...
A variation of gel electrophoresis, termed polyacrylamide gel electrophoresis (PAGE), is commonly used for separating proteins according to their molecular size by passing them through a polyacrylamide gel. Because of the varying charges associated with amino acid side chains, PAGE can be used to separate intact...
27.9K
Aqueous Solutions and Heats of Hydration
14.7K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.7K
Complexation Equilibria: Factors Influencing Stability of Complexes
369
In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
369
Ion Exchange
591
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
591


