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通过动态共价网络光聚合物进行可持续的基于 Vat 光聚合的3D打印
Sirawit Pruksawan1, Yi Ting Chong1, Wylma Zen1,2
1Institute of Materials Research and Engineering (IMRE), 2 Fusionopolis Way, Innovis #08-03, Singapore, 138634, Republic of Singapore.
Chemistry, an Asian journal
|March 20, 2024
概括
本综述探讨了用于光聚合 (VPP) 3D打印的动态共价网络 (DCN) 聚合物. 这些材料提供可回收,自我修复和可降解的原型,增强3D打印应用中的可持续性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 增材制造 增材制造 增材制造
背景情况:
- 瓦特光聚合 (VPP) 3D打印,包括SLA和DLP,在生产高精度原型方面表现出色.
- 传统的VPP材料是具有不可回收的共价交叉链的热材料,阻碍了3D打印部件的可持续使用.
- 热聚合物的有限可回收性限制了VPP 3D打印技术的环境可行性.
研究的目的:
- 审查动态共价网 (DCN) 聚合物在VPP 3D打印中的潜力.
- 突出DCN聚合物如何克服非可回收热所带来的可持续性挑战.
- 专注于可光固化的DCN聚合物,以推进可持续的VPP3D打印.
主要方法:
- 关于用于3D打印的动态共价网 (DCN) 聚合物的最新文献的综述.
- 在光聚合 (VPP) 框架内,专注于可光固化的DCN聚合物系统.
- 对用于VPP应用的DCN聚合物中可逆交联的机制的分析.
主要成果:
- 在VPP 3D打印材料中,DCN聚合物可实现可逆交联.
- 可逆交叉连接促进了印刷原型的化学/物理可回收性,自我修复性和可降解性.
- 可光固化的DCN聚合物显示出可持续3D打印的重大前景.
结论:
- 动态共价网 (DCN) 聚合物为光聚合 (VPP) 3D打印提供了一个可持续的替代方案.
- DCN的可逆性允许重新处理,修复和降解,增强材料循环性.
- 进一步开发可光固化的DCN聚合物可以彻底改变可持续的增材制造.
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