极端的Li-Mg选择性通过聚胺膜的精确离子大小差异化
Quan Peng1,2, Ruoyu Wang3, Zilin Zhao2
1College of Chemistry, Chemical Engineering and Materials Science, Innovation Center for Chemical Science & Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Soochow University, Suzhou, 215123, PR China.
Nature communications
|March 21, 2024
概括
这项研究开发了先进的纳米过 (NF) 膜,以有效地从盐水中提取. 新的OSARIP方法实现了超高的/选择性,显著改善了回收.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 从盐水中有效提取需要对Li+对Mg2+离子具有高选择性.
- 纳米过 (NF) 膜对于这种分离至关重要,但传统膜在精确的孔径大小控制方面存在困难.
- 设计具有根据Li+和Mg2+之间的尺寸差异量身定制的毛孔的NF膜是一个重大挑战.
研究的目的:
- 制造具有超高Li2+选择性的聚胺 (PA) NF膜.
- 为了提高从盐水中提取的效率.
- 为了克服传统NF膜在离子大小分离方面的局限性.
主要方法:
- 使用可溶于油的表面活性剂 (OSARIP) 修改界面聚合 (IP) 过程.
- 在PA NF膜的制造过程中,用皮佩拉 (PIP) 和三聚化 (TMC) 进行反应.
- 使用OSARIP方法精确调节膜孔大小低于Mg2+离子.
主要成果:
- 仅基于尺寸选,实现了超过99.9%的异常Mg2+排斥率.
- 已证明Li+/Mg2+的选择性比现有的压力驱动膜高一到两倍.
- 展现出优于微孔框架材料的选择性,例如COF,MOF和POP.
结论:
- 经过OSARIP修改的NF膜提供了前所未有的Li2+/Mg选择性.
- 这一进步有可能彻底改变目前的提取工艺.
- 开发的膜可以显著提高从盐水中提取的效率.
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