载荷载体运输在PbS薄膜中使用添加剂
L N Maskaeva1,2, A V Pozdin1, A Yu Pavlova3
1Ural Federal University named after the First President of Russia B.N. Yeltsin, 19 Mira str., 620002 Ekaterinburg, Russia. larisamaskaeva@yandex.ru.
Physical chemistry chemical physics : PCCP
|March 21, 2024
概括
这项研究研究了添加硫化 (PbS) 薄膜,揭示了电阻机制和电荷载体类型在含量增加时发生的转变. 这些发现表明,在杂的PbS片中存在自我补偿机制.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 半导体物理 半导体物理
背景情况:
- 多晶硫化 (PbS) 薄膜在各种电子应用中至关重要.
- 了解化半导体薄膜中的电荷传输机制对于设备优化至关重要.
- 液化沉积为制造功能性薄膜提供了一种多功能途径.
研究的目的:
- 通过水化沉积合成的添加PbS薄膜的电阻和霍尔电阻的研究.
- 分析电阻的温度依赖性,并确定电荷传输机制.
- 探索兴奋剂度对材料特性和电荷载体行为的影响.
主要方法:
- 电力和霍尔电阻测量作为温度的函数.
- 原子力显微镜 (AFM) 用于表面地形分析.
- 拉曼光谱和X射线衍射 (XRD) 用于结构特征.
主要成果:
- 电阻测量显示,从杂质带跳转到温度变量范围跳跃的交叉.
- 增加的含量导致了更高的杂质电离能.
- 电阻的温度依赖遵循一个反向的阿雷尼乌斯定律,与无序的多晶膜相一致.
- 电荷载体类型从电子转变为孔,兴奋剂增加.
- 在高的兴奋剂水平下,低电荷载体度表明存在自我补偿机制.
结论:
- 兴奋剂显著影响PbS薄膜的电传特性.
- 观察到的传输机制是无序多晶半导体材料的特征.
- 一个自我补偿机制可能在添加PbS中运作,影响载体度.
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