固体添加剂的静电潜能设计,以提高高效有机太阳能电池中聚合物捐赠者的分子序列
Zhenghong Chen1, Chuanhang Guo1, Liang Wang1
1School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China.
Small (Weinheim an der Bergstrasse, Germany)
|March 21, 2024
概括
新的素添加剂改善了聚合物供体的结构顺序,提高了有机太阳能电池中的电荷流动性. 这导致光伏设备的功率转换效率大幅提高.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 聚合物化学 聚合物化学
背景情况:
- 由于结构秩序不佳,聚合物半导体具有有限的电荷流动性.
- 在有机太阳能电池中实现高性能需要优化分子包装和充电运输.
研究的目的:
- 设计和使用新型素添加剂来调节聚合物供体PM6.的结构顺序.
- 研究添加物静电电位对聚合物包装和光伏性能的影响.
主要方法:
- 设计了五种1H--1,3(2H) 二结构化素添加剂 (INB-5F,INB-3F,INB-1F,INB-1Cl,INB-1Br).
- 分子动力学模拟用于分析添加剂-聚合物相互作用和结构变化.
- 使用PM6和L8-BO的有机太阳能电池的制造和表征.
主要成果:
- 具有降低静电潜力的添加剂促进了PM6.6在联骨干上的吸附.
- 观察到增强的外平面和内平面 π-π 堆叠,以及多个骨干堆叠.
- 面对面和边对面的分子方向的共存改善了分子包装.
- 实现了增强的电荷传输和抑制载体重组.
结论:
- 素添加剂有效调节聚合物供体结构秩序和分子包装.
- 优化的分子包装可以改善电荷传输和光伏性能.
- 在PM6/L8-BO有机太阳能电池中,最大功率转换效率达到了19.4%.
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