聚合和合离子液体――合成和应用
Qi Li1, Feng Yan2, John Texter3,4
1Department of Materials Science, School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, Jiangsu, PR China.
Chemical reviews
|March 21, 2024
概括
本综述强调了聚合离子液体 (PIL) 最近的进展,涵盖了它们的合成,性能和在能量储存和催化等领域的各种应用. 关键趋势包括新的单体设计和用于先进应用的刺激响应材料.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 聚合离子液体 (PILs) 是一个不断扩大的材料类别,具有多样化的应用.
- 体离子液体 (CILs) 桥梁离子液体单体 (ILMs) 和较大的PIL材料,表现出各种拓.
- 这一领域在过去五到六年中出现了显著的增长.
研究的目的:
- 提供最近PILs的进展和趋势的最新审查.
- 涵盖PIL和基于PIL的材料的合成,特性和应用.
- 讨论未来十年内国内生产总值 (PIL) 发展的演变.
主要方法:
- 关于PIL合成,特性和应用的文献综述.
- 分析ILM设计的趋势,聚合技术 (根链,渐进增长) 和交叉链接策略.
- 检查关键性质,如热行为,质,离子运输,自我愈合和刺激反应.
- 应用的调查,包括粘附,抗微生物涂料,催化,设备和储能等.
主要成果:
- 增加了ILM结构的多样性,包括非imidazolium核心,并扩大了逐步增长聚合的使用.
- 对CIL和PIL的受控聚合方法和交叉链接技术的进展.
- 在理解和调整PIL特性,如热过渡,粘性弹性,离子传输,自我愈合和刺激反应等方面取得了重大进展.
- 扩大应用范围,特别是储能 (超级电容器,电池,燃料电池,太阳能电池),催化和先进材料.
结论:
- 由于其可调节的特性和多样化的应用,PIL在材料科学中越来越重要.
- 合成方面的创新和对属性的更深入的理解正在推动新的应用.
- 未来的发展很可能会集中在对刺激有反应的材料和与能源相关的应用上.
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