可曲和化学稳定的金属有机混合膜用于分子分离
Zhigang Wang1, Yang Liu1,2, Liyao Wang1
1College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu, China.
ACS applied materials & interfaces
|March 21, 2024
概括
研究人员开发了一种新的无形金属有机混合体 (MOH) 膜,用于分离. 这种柔性,超薄的膜表现出出色的染料排斥和高水透性,克服了结晶材料的局限性.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 纳米技术纳米技术
背景情况:
- 像金属有机框架 (MOF) 这样的晶体多孔材料由于它们有序的孔隙,对分离膜有希望.
- 制造无缺陷的超薄晶体膜是很困难的,因为有颗粒边界.
- 无形材料提供了一个替代方法来克服这些局限性.
研究的目的:
- 开发一种无形金属有机混合体 (MOH) 膜,具有受控的微孔性.
- 创建超薄,无缺陷的膜,以实现高效的分离.
- 为了提高膜的灵活性和可加工性.
主要方法:
- 通过聚合,利用氧化和有机链接剂合成MOH膜.
- 使用界面聚合制造制造超薄膜 (低至80nm).
- 膜孔隙性,化学稳定性和分离性能的表征.
主要成果:
- 无形的MOH膜具有可调节的微孔性,与分子子相当.
- 由于强大的Ti-O键,可以实现高化学稳定性.
- 超薄膜显示出出色的染料排斥率 (>98%对于MW>690Da) 和高水透率 (55 L m−2 h−1 bar−1).
- 膜表现出显著的灵活性,提高了可加工性.
结论:
- 无形MOH膜为高级分离应用提供了结晶材料的可行替代方案.
- 开发的界面聚合法使得高性能,超薄膜的制造成为可能.
- 这些MOH膜的灵活性和可加工性提高了它们的实际用途.
相关概念视频
Potentiometry: Membrane Electrodes
568
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
568
Membrane Fluidity
152.2K
Cell membranes are composed of phospholipids, proteins, and carbohydrates loosely attached to one another through chemical interactions. Molecules are generally able to move about in the plane of the membrane, giving the membrane its flexible nature called fluidity. Two other features of the membrane contribute to membrane fluidity: the chemical structure of the phospholipids and the presence of cholesterol in the membrane.
152.2K
Extraction: Advanced Methods
446
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
446


