从铜尾矿和废水中选择性回收铜,使用具有 bis-picolylamine 功能组的合树脂
Kosisochi Ibebunjo1, Youssef El Ouardi1, John Kwame Bediako1
1School of Engineering Science, Department of Separation Science, LUT University, FI-53850, Lappeenranta, Finland.
Heliyon
|March 22, 2024
概括
这项研究介绍了Lawatit MDS TP 220,这是一种可有效从酸性工业废水和废弃物中回收铜 () 的合树脂. 树脂具有很高的结合能力和选择性,可以有效地对环境进行补救和资源回收.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 工业和采矿废水,以及铜尾矿,由于高酸度和重金属含量,是环境污染的重要来源.
- 从这些来源回收铜 (Cu) 对环境至关重要,对经济有利.
- 有 bis-picolylamine 功能组的化离子交换树脂对从酸性介质中选择性回收 Cu (II) 有效.
研究的目的:
- 为了研究Loait MDS TP 220合树脂的动力学,结合能力和选择性,用于Cu (II) 恢复.
- 评估树脂在各种条件下 (pH,度,时间,温度) 的性能及其吸附机制.
- 评估树脂的可重复使用性和环境修复潜力.
主要方法:
- 使用泽塔潜力,SEM,FTIR和XPS对Lawatit MDS TP 220的表征.
- 吸附实验以确定动力学,同热和热力学.
- 在多金属解决方案和可重复使用性测试中对选择性的评估.
主要成果:
- 快速Cu(II) 吸附动力学 (伪二阶模型) 和兰格穆尔等热体行为 (单层吸附).
- 对Cu的最大吸附能力 (qmax) 为103.9 mg/g.
- 内热,自发吸附,使用氧化进行有效脱附,在五个循环中具有很好的可重复使用性.
结论:
- 海MDS TP 220显示出高效率,容量和从酸性溶液中回收的选择性.
- 树脂的吸附机制涉及协调或化.
- 这种合树脂是从工业废水和废弃物中可持续回收铜的有希望的材料,有助于环境保护.
相关概念视频
Extraction: Advanced Methods
446
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
446
Precipitation and Co-precipitation
1.8K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.8K
Electrodeposition
633
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
633
Coagulation
292
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
292


