素诱导的NH4V4O10等级混合物作为水性离子电池的高容量阴极
相关实验视频
Updated: Jun 30, 2025

06:58
Zinc-Sponge Battery Electrodes that Suppress Dendrites
Published on: September 29, 2020
4.3K
Yaotong Li1, Chunru Zhao1, Abdukayum Abdukader2
1School of Materials Science and Engineering, Shenyang University of Technology Shenyang 110870 P. R. China wuxiang05@sut.edu.cn.
RSC advances
|March 22, 2024
概括
研究人员开发了一种用于水性离子电池 (AZIB) 的新型氨瓦纳酸盐阴极材料. 这种材料具有高容量和优异的长期稳定性,解决了AZIB技术的关键挑战.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水性离子电池 (AZIB) 提供安全性和方便性,但面临诸如慢速Zn2+扩散,阴极溶解和阳极树突等挑战.
- 开发高性能阴极材料对于推进AZIB技术至关重要.
研究的目的:
- 为AZIB应用合成和描述一种新的NH4V4O10花样结构.
- 为了研究基托桑修饰对AZIBs中氨基瓦纳酸盐电化学性能的影响.
主要方法:
- 易于通过热水合成NH4V4O10的花样结构.
- 基托桑修改以增强层间距和离子扩散.
- 对Zn//NVO-0.15C电池的电化学测试,包括容量,速率能力和循环稳定性.
主要成果:
- 合成的NH4V4O10与奇托 (NVO-0.15C) 呈现出在0.2 A g-1下520.54 mA h g-1的特定容量.
- 在1000个循环后,NVO-0.15C阴极在5.0 A g-1下保持了91%的容量保留.
- 酸盐的引入有效地扩大了 (001) 晶体平面间距,促进了 Zn2+ 离子的储存.
结论:
- 修改后的瓦纳酸显示出AZIBs的优异离子储存能力.
- 该NVO-0.15C材料显示承诺作为安全和高效的储能设备的高性能阴极.
相关概念视频
Formation of Complex Ions
23.6K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.6K
Extraction: Advanced Methods
446
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
446
Batteries and Fuel Cells
27.3K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.3K

