来自卢瓦尔河口 (法国大西洋海岸) 的盆地区的有机酸盐添加剂和微塑料
J Castro-Jiménez1, Y Aminot1, N Bely1
1IFREMER, CCEM Contamination Chimique des Écosystèmes Marins, F-44000 Nantes, France.
Marine pollution bulletin
|March 23, 2024
概括
有机酸盐 (OPEs) 和微塑料 (MPs) 在卢瓦尔河口沉积物和海Scrrobicularia plana.中同时存在. 虽然MP很丰富,但它们与OPE的相关性有限,这表明MP不是一个主要的现场OPE来源.
科学领域:
- 环境化学环境化学
- 海洋生物学 海洋生物学
- 生态毒理学 生态毒理学
背景情况:
- 有机酸 (OPE) 是广泛使用的阻燃剂和增塑剂.
- 微塑料 (MP) 是普遍存在的环境污染物.
- 地环境是OPE和MP的潜在沉没点.
研究的目的:
- 为了调查OPEs和MPs在卢瓦尔河口的盆地区的同时发生.
- 测量沉积物中的OPEs和MPs度以及Scrobicularia plana.贝中的数量.
- 评估MP作为OPE来源和OPE生物积累的潜在作用.
主要方法:
- 从卢瓦尔河口收集了沉积物和Scrobicularia plana的样本.
- 使用气体染色体质谱测量测量了13种三OPE和4种二OPE的度.
- 微塑料被提取并定量.
- 计算了生物沉积积积因子 (BSAFs).
主要成果:
- 在潮间沉积物中发现了MPs,13tri-OPEs和4di-OPEs的中位数度较高,特别是在细颗粒和高人为压力地区.
- 在夏季,Scrobicularia plana表现出较高的三OPE度.
- 聚乙烯是主要的MP类型. 三二甲基酸盐 (TEHP),其代谢物 (BEHP) 和三二一甲基酸盐 (TCIPP) 是最丰富的OPE.
- BSAFs表明了化OPEs的生物积累潜力,夏季暴露率更高.
- 在沉积物中没有发现OPE和MP之间的显著相关性.
结论:
- OPEs和MPs同时发生在卢瓦尔河口的盆地区.
- 在这种环境中,微塑料似乎不是一个重要的现场OPE来源.
- 化OPEs在Scrrobicularia plana中显示出生物积累的潜力,季节性变化.
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