碳钢在二乙二胺溶液中的腐蚀行为,用于燃烧后的CO2捕获
Xinyue Chen1,2, Yongkang Cui1,2, Shujuan Wang1,2,3,4
1Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China.
ACS omega
|March 25, 2024
概括
乙二胺 (DETA) 溶液减少碳钢腐蚀随着二氧化碳负载的增加,与MEA不同. 这一发现对于在燃烧后碳捕获技术中开发有效的腐蚀抑制剂至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 电化学 电化学 电化学
背景情况:
- 乙二胺 (DETA) 对于二氧化碳捕获至关重要,但会导致设备腐蚀.
- 了解腐蚀机制是减轻材料降解的关键.
研究的目的:
- 在DETA解决方案中研究20#碳钢的腐蚀行为.
- 为了比较DETA的腐蚀效应与单乙醇胺 (MEA).
- 为了阐明二氧化碳负载对腐蚀率的影响.
主要方法:
- 减肥的测量方法 减肥的测量方法
- 电化学技术 电化学技术 电化学技术
- 扫描电子显微镜/能量分散光谱 (SEM/EDS) 技术
- 在X射线衍射 (XRD) 中.
主要成果:
- 在DETA中腐蚀率取决于温度,类似于MEA.
- 在DETA中增加的CO2负载降低了碳钢的腐蚀率,与MEA相反.
- 由于Fe2+和CO32-度较低,没有保护性FeCO3层.
结论:
- DETA表现出独特的腐蚀行为,受二氧化碳负载的影响.
- 由于DETA的复杂化能力和Fe2+的溶解性,可以解释腐蚀的减少.
- 这些发现支持开发基于DETA的碳捕获系统的腐蚀抑制剂.
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