研究不同MGO脱硫剂在烟气脱硫中的溶解动力学
Mengyu Ma1, Hongge Zhao1, Peng Hu1
1School of Chemistry and Pharmaceutical Engineering, Huanghuai University, Zhumadian 463000, P. R. China.
ACS omega
|March 25, 2024
概括
这项研究通过减少颗粒大小和添加水友群来增强氧化 (MgO) 脱硫剂,改善分散和溶解率,以实现高效的工业应用.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 氧化 (MgO) 是一个关键的脱硫剂,但它的效率受到粒子大小和分散的限制.
- 提高MgO脱硫器性能需要增强表面性能和控制颗粒大小.
研究的目的:
- 通过将颗粒大小降低到纳米级,并引入水友性功能群来提高MgO脱硫器的性能.
- 研究这些修改对分散,水友性,稳定性和溶解动力学的影响.
主要方法:
- 使用机械研磨来减少MgO颗粒大小.
- 在MgO表面上引入了水友性功能组.
- 进行了稳定性测试 (泽塔潜力,沉积率) 和溶解反应/动力学实验.
主要成果:
- 经过修改的MgO脱硫剂 (5重量%) 在30天后表现出极好的稳定性 (泽塔电位>50mV,沉率≤7%).
- 减少粒子大小和增加水友性显著加快了MgO溶解速率并降低了明显的激活能量.
- 改进的MgO纳米流体的溶解率提高,减少质量转移阻力和延长透时间.
结论:
- MgO脱硫剂的表面修饰和纳米化增强了它们的分散性,水友性和溶解动力学.
- 改进的方法为大规模生产高性能MgO脱硫剂提供了基础.
- 增强的MgO纳米流体通过减少质量转移限制,提高了脱硫过程的效率.
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