剪切诱导结晶对叶片结构缩表面活性剂溶液复杂粘度的影响
Parth U Kelkar1, Matthew Kaboolian1, Ria D Corder1,2
1School of Materials Engineering, Purdue University, West Lafayette, IN, 47907, USA. erk@purdue.edu.
Soft matter
|March 26, 2024
概括
低温导致表面活性剂结晶,增加缩溶液中的粘度. 了解这些低温行为对于可持续的消费品制造至关重要,比如冷水洗衣剂.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 合体和表面化学
背景情况:
- 缩的表面活性剂溶液在消费品中至关重要.
- 了解低温行为对于产品的稳定性和性能至关重要.
- 目前存在关于在低温下结构-属性-处理关系的知识差距.
研究的目的:
- 在低温下研究集中表面活性剂溶液中的物质关系.
- 为了阐明温度,冷却时间和剪切对表面活性剂相位行为的影响.
- 为可持续的产品设计建立结构-财产-加工关系.
主要方法:
- 风学实验用于测量粘度和流动行为.
- 交叉极化显微镜用于可视化结构变化.
- 热量测量以检测相位过渡.
- 用于结构分析的小角度X射线散射 (SAXS).
主要成果:
- 在5°C和10°C的表面活性剂结晶导致极高的粘度.
- 对于多层层囊泡 (20°C) 和焦点形缺陷 (90°C) 也观察到类似的散流行为.
- 剪切诱导的结晶导致在高温下复杂的粘度峰值.
结论:
- 低温表面活性剂结晶显著影响粘度.
- 温度和剪切等加工参数影响材料的散装流和结构.
- 这项研究为优化基于表面活性剂的产品用于低温应用提供了必要的数据.
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