来自Au39(SR)29纳米团的明亮的近红外辐射
Zhongyu Liu1, Lianshun Luo1, Jie Kong2
1Department of Chemistry, Carnegie Mellon University. Pittsburgh, PA 15213, USA. rongchao@andrew.cmu.edu.
Nanoscale
|March 26, 2024
概括
原子精确的金纳米集群 (AuNCs) 显示出高的近红外 (NIR) 光发光. Au39(PET) 29通过双极-双极相互作用表现出可调节的发射,增强其对光电子的潜力.
科学领域:
- 纳米材料科学 科学 纳米材料科学
- 摄影化学的使用.
- 固态物理 固态物理
背景情况:
- 原子精确的金纳米集群 (AuNC) 对于在近红外 (NIR) 区域需要高光发光量子产量 (PLQY) 的应用至关重要.
- 了解AuNCs的光发光机制对于推进它们的基础科学和实际实用性至关重要.
研究的目的:
- 合成和表征一个分子纯度,高发光的AuNC与NIR发射.
- 为了阐明合成的AuNC的光发光机制.
- 研究固态环境对AuNC光发光和PLQY的影响.
主要方法:
- Au39(PET) 29纳米集群的合成.
- 稳态和时间分辨率光发光 (PL) 谱学.
- 取决于温度的PL测量.
- 在聚乙烯薄膜中嵌入的AuNCs的制造.
主要成果:
- 一个分子纯的Au39(PET) 29纳米团被合成,具有NIR发射 (915 nm) 和19%的PLQY.
- 发射机制包括快速光,热激活延迟光 (TADF) 和光.
- 在聚乙烯矩阵中嵌入Au39(PET) 29,通过缩小S1-T1能量差距,促进更快的系统间交叉 (ISC) 和反向系统间交叉 (RISC),将总PLQY提高到32%.
结论:
- Au39(PET) 29纳米团表现出复杂的排放机制,其中TADF和光有着显著的贡献.
- 固态效应,特别是双极双极相互作用,可以被利用来增强AuNC光发光.
- 这些发现凸显了Au39(PET) 29在成像,传感和光电子领域的先进应用中的潜力.
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