带有联合断裂连接器的二度接收器使得高效和机械稳固的有机太阳能电池成为可能
Yafei Ding1, Waqar Ali Memon1, Di Zhang2
1Shenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055, China.
研究人员为内在可拉伸的有机太阳能电池 (IS-OSC) 开发了新的二度受体. 这些接受器实现了高功率转换效率和显著的机械强度,克服了现有材料的局限性.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 太阳能光伏发电是如何实现的
背景情况:
- 设计高效且机械坚固的接受器对于内在可拉伸的有机太阳能电池 (IS-OSC) 至关重要.
- 现有的可拉伸聚合物受体具有有限的效率,而高性能小分子受体则易碎.
研究的目的:
- 为了合成和评估使用乙烯 - 乙烯 - 乙烯 (TAT) 结合 - 断裂链接器的新型二元化受体.
- 研究连接点和素替代对分子性质和设备性能的影响.
主要方法:
- 合成四个具有不同连接位和素替代的二元化受体.
- 电子结构的表征,聚合行为和电荷传输特性.
- 刚性和内在可拉伸的有机太阳能电池 (OSC) 的制造和测试.
主要成果:
- 分子结构的优化导致了混合膜中的合理相分离,增强了激子解离和抑制电荷重组.
- 基于FDY-m-TAT的刚性OSC实现了18.07%的功率转换效率 (PCE).
- 基于FDY-m-TAT的IS-OSC显示高PCE14.29%和破裂开始菌株 (COS) 18.23%,表现优于基于Y6的对应物.
结论:
- 具有合断裂链接器的二度受体显示出开发高效和机械强大的有机太阳能电池的巨大潜力.
- 设计策略为克服IS-OSC中效率和伸展性之间的权衡提供了一条途径.
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