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Updated: Jul 12, 2026

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用移植的Si-doped γ-graphyne作为可逆储存宿主材料

Nidhi Duhan1, T J Dhilip Kumar1

  • 1Quantum Dynamics Lab, Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar 140001, India. dhilip@iitrpr.ac.in.

Physical chemistry chemical physics : PCCP
|March 26, 2024
PubMed
概括

研究人员开发了一种新型的功能化Si-doped γ-graphyne (Li8SiG),用于高效的 (H2) 储存. 这种材料显示出高的重力测量能力和可逆的2吸收,满足了能源部对可持续能源应用的目标.

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相关概念视频

Acid Halides to Ketones: Gilman Reagent01:14

Acid Halides to Ketones: Gilman Reagent

Lithium dialkyl cuprate, also known as Gilman reagents, selectively reduces acid halides to ketones. The acid chloride is treated with Gilman reagent at −78 °C in the presence of ether solution to produce a ketone in good yield.
As shown below, the mechanism proceeds in two steps. First, one of the alkyl groups of the reagent acts as a nucleophile and attacks the acyl carbon of the acid chloride to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen double...