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Updated: Jun 29, 2025

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

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通过电子结构调节进行增强的性进化反应:通过稀土TM合金激活PtRh

Qingqing Li1, Botao Zhang2, Chang Sun1

  • 1Nankai University, Tianjin Key Laboratory of Rare-earth Materials and Applications, School of Materials Science and Engineering, Centre of Rare Earth and Inorganic Functional Materials, Tianjin, 300350, P. R. China.

Small (Weinheim an der Bergstrasse, Germany)
|March 27, 2024
PubMed
概括

一种新的PtRhTm合金显示了性演化反应 (HER) 的增强性能,这对于绿色生产至关重要. 这种先进的电催化剂与传统材料相比,提供了更高的效率.

关键词:
性进化反应的反应转移费用 转移费用 转移费用 转移费用电催化剂是一种电催化剂.稀土合金是一种稀土合金.

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
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